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Gas reference materials

Standard primary reference gases

Easy access to reference gas mixtures

NPL provides a wide range of reference gas mixtures that can be tailored to suit the needs of multiple industry sectors. Preparation of these bespoke mixtures can however increase lead times. In order to reduce those lead times, NPL has launched a new range of standard gas mixtures which represent compositions that are in the highest demand and in some cases, where stability is good, may be made in advance to further reduce lead times.

Below is the current list of standards mixtures that are available. Each is provided in a 10 litre cylinder with a valve fitted as per the description in the table. Concentration uncertainty and mixture stability are dependent upon the specific mixture composition and specified below for each standard. The make-up gases used are either pure nitrogen or synthetic air which is composed of 79% nitrogen and 21% oxygen.

NPL remains committed to continuing its full range of gas mixtures and if the exact composition is not listed below, please contact us for a more bespoke quotation.

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Breath analysis standards

Standard mixtures of ethanol and acetone in nitrogen or synthetic air are listed below.

Mixture

Nominal concentrations

Uncertainty

Stability

Valve

Order reference

Ethanol (EtOH) in nitrogen

50 ppm

0.8%

1 year 6 months

BS341 No. 14

QE12-1130-REF-GAS-ETHANOL-N50-UKASMRA

100 ppm

0.8%

3 years

BS341 No. 14

QE12-1130-REF-GAS-ETHANOL-N100-UKASMRA

200 ppm

0.8%

5 years

BS341 No. 14

QE12-1130-REF-GAS-ETHANOL-N200-UKASMRA

276 ppm

0.8%

5 years

BS341 No. 14

QE12-1130-REF-GAS-ETHANOL-N276-UKASMRA

Ethanol (EtOH) in synthetic air

54.4 ppm

0.8%

1 year 6 months

BS341 No. 14

QE12-1130-REF-GAS-ETHANOL-A54-UKASMRA

82.3 ppm

0.8%

2 years

BS341 No. 14

QE12-1130-REF-GAS-ETHANOL-A82-UKASMRA

137 ppm

0.8%

3 years

BS341 No. 14

QE12-1130-REF-GAS-ETHANOL-A137-UKASMRA

191 ppm

0.8%

5 years

BS341 No. 14

QE12-1130-REF-GAS-ETHANOL-A191-UKASMRA

245 ppm

0.8%

5 years

BS341 No. 14

QE12-1130-REF-GAS-ETHANOL-A245-UKASMRA

301 ppm

0.8%

5 years

BS341 No. 14

QE12-1130-REF-GAS-ETHANOL-A301-UKASMRA

354 ppm

0.8%

5 years

BS341 No. 14

QE12-1130-REF-GAS-ETHANOL-A354-UKASMRA

Acetone (C3H6O) in synthetic air

40 ppm

2.0%

2 years

BS341 No. 14

QE12-1070-REF-GAS-ACETONE-A40-UKASMRA

60 ppm

2.0%

2 years

BS341 No. 14

QE12-1070-REF-GAS-ACETONE-A60-UKASMRA

220 ppm

2.0%

2 years

BS341 No. 14

QE12-1070-REF-GAS-ACETONE-A220-UKASMRA

Emissions monitoring standards

Standard binary mixtures that can be supplied within specific concentration ranges are shown in the table below. Please specify the desired concentration within these bands when ordering.

Mixture

Nominal concentrations

Uncertainty

Stability

Valve

Order reference

 

 

 

 

 

 

Propane (C3H8) in nitrogen

10 ppm - 1000 ppm

0.5%

5 years

BS341 No. 14

QE11-1050-REF-GAS-PROPANE-N10RNG-UKASMRA

Propane (C3H8) in synthetic air

10 ppm - 1000 ppm

0.5%

5 years

BS341 No. 14

QE11-1050-REF-GAS-PROPANE-A10RNG-UKASMRA

Sulphur dioxide (SO2) in nitrogen

10 ppm - 49 ppm

1.0%

2 years

DIN 477 No.8

QE11-2020-REF-GAS-SO2-N10RNG-UKASMRA

50 ppm - 999 ppm

0.8%

5 years

DIN 477 No.8

QE11-2020-REF-GAS-SO2-N50RNG-UKASMRA

1000 ppm - 5000 ppm

0.4%

5 years

DIN 477 No.8

QE11-2020-REF-GAS-SO2-N1000RNG-UKASMRA

Sulphur dioxide (SO2) in air

10 ppm - 49 ppm

1.0%

2 years

DIN 477 No.8

QE11-2020-REF-GAS-SO2-A10RNG-UKASMRA

50 ppm - 999 ppm

0.8%

5 years

DIN 477 No.8

QE11-2020-REF-GAS-SO2-A50RNG-UKASMRA

1000 ppm - 5000 ppm

0.4%

5 years

DIN 477 No.8

QE11-2020-REF-GAS-SO2-A1000RNG-UKASMRA

Carbon monoxide (CO) in nitrogen

10 ppm - 3.4%

0.5%

5 years

BS341 No. 14

QE11-2030-REF-GAS-CO-N10RNG-UKASMRA

3.5% - 10%

0.4%

5 years

BS341 No. 15

QE11-2030-REF-GAS-CO-N35PCRNG-UKASMRA

Carbon dioxide (CO2) in nitrogen

10 ppm - 20%

0.3% - 0.5%

5 years

BS341 No. 14

QE11-2060-REF-GAS-CO2-N10RNG-UKASMRA

Carbon dioxide (CO2) in synthetic air

100 ppm - 2000 ppm

0.3% - 0.5%

5 years

BS341 No. 14

QE11-2060-REF-GAS-CO2-A100RNG-UKASMRA

Methane (CH4) in nitrogen

10 ppm - 2%

0.5%

5 years

BS341 No. 14

QE11-2060-REF-GAS-CH4-N10RNG-UKASMRA

Methane (CH4) in synthetic air

10 ppm - 1000 ppm

0.5%

5 years

BS341 No. 15

QE11-2060-REF-GAS-CH4-A10RNG-UKASMRA

Oxygen (O2) in nitrogen

10 ppm - 21%

0.3% - 0.5%

5 years

BS341 No. 14

QE11-2070-REF-GAS-O2-N10RNG-UKASMRA

Hydrogen sulphide (H2S) in nitrogen

10 ppm - 500 ppm

2% - 3%

5 years

DIN 477 No.1

QE13-1050-REF-GAS-H2S-N10RNG-UKASMRA

Additional binary mixtures that are supplied in discrete concentrations are shown in the table below.

Mixture

Nominal concentrations

Uncertainty

Stability

Valve

Order reference

Nitrogen monoxide (NO) in nitrogen
(Fast turnaround standard)

50 ppm

0.5%

5 years

BS341 No. 14

QE11-2010-REF-GAS-NO-N50FAST-UKASMRA

Nitrogen monoxide (NO) in nitrogen

10 ppm

1.0%

2 years

BS341 No. 14

QE11-2010-REF-GAS-NO-N10-UKASMRA

20 ppm

1.0%

2 years

BS341 No. 14

QE11-2010-REF-GAS-NO-N20-UKASMRA

25 ppm

1.0%

2 years

BS341 No. 14

QE11-2010-REF-GAS-NO-N25-UKASMRA

30 ppm

0.8%

5 years

BS341 No. 14

QE11-2010-REF-GAS-NO-N30-UKASMRA

35 ppm

0.8%

5 years

BS341 No. 14

QE11-2010-REF-GAS-NO-N35-UKASMRA

45 ppm

0.8%

5 years

BS341 No. 14

QE11-2010-REF-GAS-NO-N45-UKASMRA

70 ppm

0.5%

5 years

BS341 No. 14

QE11-2010-REF-GAS-NO-N70-UKASMRA

100 ppm

0.5%

5 years

BS341 No. 14

QE11-2010-REF-GAS-NO-N100-UKASMRA

250 ppm

0.5%

5 years

BS341 No. 14

QE11-2010-REF-GAS-NO-N250-UKASMRA

500 ppm

0.5%

5 years

BS341 No. 14

QE11-2010-REF-GAS-NO-N500-UKASMRA

Environmental gas standards

Standard binary mixtures that can be supplied within specific concentration ranges or discrete ones are shown in the table below. Please specify the desired concentration for those with ranges when ordering. Additional notes for these mixtures are shown below the table.

Mixture

Nominal concentrations

Uncertainty

Stability

Valve

Order reference

6 Component BTEX mixture in nitrogen

4 ppb - 10 ppb

2% - 3%

5 years

DIN 477 No. 1

QE12-1030-REF-GAS-BTEX-N4BRNG-UKASMRA

100 ppb

2% - 3%

5 years

DIN 477 No. 1

QE12-1030-REF-GAS-BTEX-N100B-UKASMRA

200 ppb

2% - 3%

5 years

DIN 477 No. 1

QE12-1030-REF-GAS-BTEX-N200B-UKASMRA

30 component ozone precursor mixture in nitrogen

4 ppb

2% - 5%

5 years

DIN 477 No. 1

QE12-1030-REF-GAS-OZP30-N4B-UKASMRA

5 ppb

2% - 5%

5 years

DIN 477 No. 1

QE12-1030-REF-GAS-OZP30-N5B-UKASMRA

100 ppb

2% - 5%

5 years

DIN 477 No. 1

QE12-1030-REF-GAS-OZP30-N100B-UKASMRA

200 ppb

2% - 5%

5 years

DIN 477 No. 1

QE12-1030-REF-GAS-OZP30-N200B-UKASMRA

Benzene in nitrogen

1 ppb - 10 ppb

2% - 3%

2 years

DIN 477 No. 1

QE12-1030-REF-GAS-BENZENE-N1BRNG-UKASMRA

20 component mixture for PTR-MS calibration

1 ppm (nominal)

3% - 10%

1 year

DIN 477 No. 8

QE12-1070-REF-GAS-PTRMS-N1STD-UKAS

8 component mixture for SIFT-MS calibration

2 ppm (nominal)

3% - 10%

1 year

DIN 477 No. 1

QE12-1070-REF-GAS-SIFTMS-N1STD-UKAS

Notes

  1. BTEX and Ozone Precursor Mixtures: NPL will certify the total amount fraction of both m-xylene and p-xylene together as separation cannot be achieved.
  2. PTRMS and SIFT MS Calibration Standard: Each component at nominally at 1 μmol/mol (ppm).

If you would like to order any of these mixtures or have questions about them, please contact us

Contact us