National Physical Laboratory

List of standards led by NPL for ISO/TC 201 – Surface Chemical Analysis

The following are the details of the standards that have been led by the Surface and Nanoanalysis team at NPL for ISO/TC 201.

Standards in progress:

ISO/WD 11775 - Surface chemical analysis - Scanning probe microscopy - Determination of cantilever normal spring constants
Scope: This International Standard describes methods for the determination of normal spring constants for atomic force microscope cantilevers. The methods are provided under the three categories of dimensional, static experimental and dynamic experimental methods. The method chosen depends on the purpose and convenience to the analyst.


ISO 13084 - Surface chemical analysis - Secondary ion mass spectrometry - Calibration of the mass scale for a time of flight secondary ion mass spectrometer
Scope: This International Standard specifies a method to optimise the mass calibration accuracy in time-of-flight SIMS instruments used for general analytical purposes. It is only applicable to time-of-flight instruments but is not restricted to any particular instrument design. Guidance is provided for some of the instrumental parameters that may be optimised using this procedure and the types of generic peaks suitable to calibrate the mass scale for optimum mass accuracy.


ISO 14701 - Surface chemical analysis - X-ray photoelectron spectroscopy - Measurement of silicon oxide thickness

Scope: This International Standard specifies several methods for measuring the oxide thickness at the surfaces of (100) and (111) silicon wafers as an equivalent thickness of silicon dioxide when measured using X-ray photoelectron spectroscopy. It is only applicable to flat, polished samples and for instruments that incorporate an Al or Mg X-ray source, a sample stage that permits defined photoelectron emission angles and a spectrometer with an input lens that may be restricted to less than a 6˚ cone semi-angle. For thermal oxides in the range 1 to 8 nm thickness, using the best method described in this International Standard, uncertainties at a 95% confidence level around 2% may be typical and around 1% at optimum. A simpler method is also given with slightly poorer, but often adequate, uncertainties.


ISO 14976 - Surface chemical analysis - Data transfer format

Scope This international standard specifies a Format to transfer data from computer to computer via parallel interfaces or via serial interfaces over direct wire, telephone line, local area network or other communications link. The transferred data is encoded only in those characters that appear on a normal display or printer. The format is suitable for AES, EDX, FABMS, ISS, SIMS, SNMS, UPS, XPS, XRF and similar analytical methods. It covers spectra, elemental maps, depth profiles and sequences of data resulting from a variety of experiments. For an overview see Surface and Interface Analysis 27 (1999) 693 - 694.


ISO 15472 - Surface chemical analysis - X-ray photoelectron spectrometers - Calibration of energy scales

Scope: This international standard specifies a method for calibrating the binding energy scale of X-ray photoelectron spectrometers, for general analytical purposes, using unmonochromated Al or Mg X-rays or monochromated Al X-rays. It is only applicable to instruments which incorporate an ion gun for sputter cleaning. This standard further specifies a method to establish a calibration schedule, to test for the binding energy scale linearity at one intermediate energy, to confirm the uncertainty of the scale calibration at one low and one high binding energy value, to correct for small drifts of that scale and to define the expanded uncertainty of the calibration of the binding energy scale for a confidence level of 95%. This uncertainty includes contributions for behaviours observed in interlaboratory studies but does not cover all of the defects that could occur. This standard is not applicable to instruments with binding energy scale errors that are significantly non-linear with energy, to instruments operated in the constant retardation ratio mode at retardation ratios less than 10, to instruments with a spectrometer resolution worse than 1,5 eV, or to instruments requiring tolerance limits of +0,03 eV or less. This standard does not provide a full calibration check, which would confirm the energy measured at each addressable point on the energy scale and which should be performed according to the manufacturer's recommended procedures. For some of the technical details see Surface and Interface Analysis 26 (1998) 617 - 641 and Surface and Interface Analysis 26 (1998) 642 - 649.


ISO/CD 17862 - Surface chemical analysis - Secondary ion mass spectrometry - Linearity of intensity scale in single ion counting time-of-flight mass analysers

Scope: This International Standard specifies a method for determining the maximum count rate for an acceptable limit of divergence from linearity of the intensity scale in single ion counting time-of-flight secondary ion mass spectrometers using a test based on isotopic ratios in spectra from poly(tetrafluoroethylene) (PTFE). It also includes a method to correct for intensity non-linearity arising from intensity lost from a microchannel plate (MCP) or scintillator and photomultiplier followed by a time-to-digital converter (TDC) detection system caused by secondary ions arriving during its dead time. The correction can increase the intensity range for 95% linearity by a factor of up to more than 50 so that a higher maximum count rate can be employed for those spectrometers for which the relevant correction equations have been shown to be valid. This International Standard may also be used to confirm the validity of instruments in which the dead time correction is already made but in which further increases may or may not be possible.


ISO 17973 - Surface chemical analysis - Medium resolution Auger electron spectrometers - Calibration of energy scales for elemental analysis

Scope: This international standard specifies a method for calibrating the kinetic energy scale of Auger electron spectrometers with an uncertainty of 3 eV for general analytical use for identifying elements at surfaces. It is suitable for instruments used in either the direct mode or the differential mode where the resolution is equal to or less than 0,5% and the modulation amplitude for the differential mode, if used, is 2 eV peak-to-peak. The spectrometer must be equipped with an inert gas ion gun or other method for sample cleaning and with an electron gun capable of operating at 4 keV or higher beam energy. This International Standard further specifies a method to establish a calibration schedule. For some of the technical details see Journal of Electron Spectroscopy 83 (1997) 197 - 208 and Journal of Electron Spectroscopy 97 (1997) 235 - 241.


ISO 17974 - Surface chemical analysis - High resolution Auger electron spectrometers - Calibration of energy scales for elemental and chemical state analysis

Scope: This international standard specifies a method for calibrating the kinetic energy scales of Auger electron spectrometers, for elemental and chemical state analysis at surfaces. It is only applicable to instruments which incorporate an ion gun for sputter cleaning. This International Standard further specifies a method to establish a calibration schedule, to test for the kinetic energy scale linearity at one intermediate energy, to confirm the uncertainty of the scale calibration at one low and one high kinetic energy value, to correct for small drifts of that scale and to define the expanded uncertainty of the calibration of the kinetic energy scale for a confidence level of 95%. This uncertainty includes contributions for behaviours observed in interlaboratory studies but does not cover all of the defects that could occur. This International Standard is not applicable to instruments with kinetic energy scale errors that are significantly non-linear with energy, to instruments operated at relative resolutions poorer than 0,2% in the constant DE/E mode or poorer than 1,5 eV in the constant DE mode, to instruments requiring tolerance limits of +0,05 eV or less, or to instruments equipped with an electron gun that cannot be operated in the energy range 5 keV to 10 keV. This standard does not provide a full calibration check, which would confirm the energy measured at each addressable point on the energy scale and which should be performed according to the manufacturer's recommended procedures. For some of the technical details see Journal of Electron Spectroscopy 83 (1997) 197 - 208 and Journal of Electron Spectroscopy 97 (1997) 235 - 241.


ISO 18115 - Surface chemical analysis - Vocabulary and vocabulary supplement

ISO 18115 - Surface chemical analysis - Vocabulary - Part 1: General terms and terms used in spectroscopy

ISO 18115 - Surface chemical analysis - Vocabulary - Part 2: Terms used in scanning-probe microscopy

Scope: Part 1 - ISO 18115 defines terms for surface chemical analysis. Part 1 covers general terms and those used in spectroscopy whereas Part 2 covers terms used in scanning-probe microscopy.

List of terms defined in ISO 18115 - Surface Chemical Analysis - Vocabulary

A family tree of SPM acronyms, and annotated figures of the design of complex probes and probe assembly


ISO 21270 - Surface chemical analysis - X-ray photoelectron and Auger electron spectrometers - Linearity of intensity scale
Scope: This international standard specifies a method for determining the maximum count rate for an acceptable limit of divergence from linearity of the intensity scale of Auger and X-ray photoelectron spectrometers. It also includes methods to extend that maximum count rate that are appropriate for some spectrometers. For some of the technical details see Journal of Electron Spectroscopy 104 (1999) 73 - 89.


ISO 22048 - Surface chemical analysis - Information format - Static secondary ion mass spectrometry
Scope: This international standard provides a digital format to store and transfer, between computers in a compact way, important calibration and instrumental parameter data necessary to make effective use of spectral data files from static SIMS instruments. This standard format is designed to supplement the data transfer format ISO 14976.


ISO 23830 - Surface chemical analysis - Secondary ion mass spectrometry - Repeatability and constancy of the relative-intensity scale in static secondary-ion mass spectrometry

Scope: This international standard specifies a method for confirming the repeatability and constancy of the positive-ion relative-intensity scale of static secondary-ion mass spectrometers, for general analytical purposes. It is only applicable to instruments that incorporate an electron gun for charge neutralization. It is not intended to be a calibration of the intensity/mass response function. That calibration may be made by the instrument manufacturer or another organization. The present method provides data to confirm the constancy of relative intensities with instrument usage. Guidance is given on some of the instrument settings that may affect this constancy.


ISO 24236 - Surface chemical analysis - Auger electron spectroscopy - Repeatability and constancy of intensity scales

Scope: This international standard specifies a method for evaluating the constancy and repeatability of the intensity scale of Auger electron spectrometers, for general analytical purposes, using an electron gun with a beam energy of 2 keV or greater. It is only applicable to instruments that incorporate an ion gun for sputter cleaning. It is not intended to be a calibration of the intensity/energy response function. That calibration may be made by the instrument manufacturer or other organisation. The present procedure provides data to evaluate and confirm the accuracy with which the intensity/energy response function remains constant with instrument usage. Guidance is given to some of the instrumental settings that may affect this constancy.


ISO 24237 -; Surface chemical analysis - X-ray photoelectron spectroscopy - Repeatability and constancy of intensity scales

Scope: This international standard specifies a method for evaluating the repeatability and constancy of the intensity scale of X-ray photoelectron spectrometers, for general analytical purposes, using unmonochromated Al or Mg X-rays or monochromated Al X-rays. It is only applicable to instruments that incorporate an ion gun for sputter cleaning. It is not intended to be a calibration of the intensity/energy response function. That calibration may be made by the instrument manufacturer or other organisation. The present method provides data to evaluate and confirm the accuracy with which the intensity/energy response function remains constant with instrument usage. Guidance is given to some of the instrument settings that may affect this constancy.

Last Updated: 5 Dec 2012
Created: 16 Jun 2010