National Physical Laboratory

LPG, LNG and other liquid hydrocarbon standard mixtures

NPL can produce LPG (liquefied petroleum gas), LNG (liquefied natural gas) and other liquid hydrocarbon standards in two forms of vessel technology: constant pressure (piston) cylinders or dual-port valve dip-tube cylinders.

Constant pressure cylinder Dual-port valve dip-tube cylinder
      Constant pressure cylinder on the left             Dual-port valve dip-tube cylinder on the right


The constant pressure cylinders employ a piston as a physical barrier maintained by high pressure, which ensures that the composition of the mixture remains. The cylinders also possess an integral mixer that guarantees users draw homogenous samples of constant composition. Cylinders of 300mL, 500mL or 1L volume are available.

The dual-port valve dip-tube cylinders do not have any physical barrier between the gas and the liquid hydrocarbon mixture, however the dual port valve does allow for a overpressure of gas (usually helium) to be maintained. These cylinders have an internal volume of 10L.

Some example liquid hydrocarbon mixtures are shown in the table below. Other mixtures are available and it may also be possible to include components not listed in the table. Please contact us for further information.

Component Amount Fraction (% mol/mol)
Liquefied Petroleum Gas (C3 rich) Liquefied Petroleum Gas (C4 rich) Liquefied Natural Gas
Methane - - 80
Ethane 0.5
-
10
Propane
70
17.5
2.5
Propene 15
4.0
-
iso-Butane 2.0
10 2.0
n-Butane
5.0 60 2.0
But-1-ene
1.5 2.5 -
iso-Butene
1.0 2.0 -
trans-2-Butene
- 1.75 -
cis-2-Butene
- 1.25 -
iso-Pentane
- 0.5 1.0
n-Pentane
- 0.5 1.5
n-Hexane
- - 1.0


Guide to handling liquid hydrocarbon mixtures in constant pressure cylinders Adobe Acrobat PDF file

Contact

Customer Service tel: +44 20 8943 8637
E-mail: gases_enquiries@npl.co.uk

Last Updated: 13 Mar 2013
Created: 27 Jul 2010